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Fri, 16 Nov 2007 09:37:54

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Cherdust2002

The Havens <thehavens

Re: [graffis-l]HYDROGEN AS FUEL

 

New Method Converts Organic Matter To Hydrogen

Fuel Easily And Effic

Posted by: " Mark Graffis "

mgraffis

mgraffis

 

Thu Nov 15, 2007 5:53 pm (PST)

http://www.sciencedaily.com/releases/2007/11/071112172203.htm

New Method Converts Organic Matter To Hydrogen Fuel Easily And

Efficiently ScienceDaily (Nov. 13, 2007) ­ Hydrogen as an everyday,

environmentally friendly fuel source may be closer than we think,

according to Penn State researchers. " The energy focus is currently on ethanol as a fuel, but

economical ethanol from cellulose is 10 years down the road, " says

Bruce E. Logan, the Kappe professor of environmental engineering.

" First you need to break cellulose down to sugars and then bacteria

can convert them to ethanol. " Logan and Shaoan Cheng, research associate, suggest a method based on

microbial fuel cells to convert cellulose and other biodegradable organic

materials directly into hydrogen.

The researchers used naturally occurring bacteria in a microbial

electrolysis cell with acetic acid -- the acid found in vinegar. Acetic

acid is also the predominant acid produced by fermentation of glucose or

cellulose. The anode was granulated graphite, the cathode was carbon with

a platinum catalyst, and they used an off-the-shelf anion exchange

membrane. The bacteria consume the acetic acid and release electrons and

protons creating up to 0.3 volts. When more than 0.2 volts are added from

an outside source, hydrogen gas bubbles up from the liquid. " This process produces 288 percent more energy in hydrogen than

the electrical energy that is added to the process, " says Logan. Water hydrolysis, a standard method for producing hydrogen, is only

50 to 70 percent efficient. Even if the microbial electrolysis cell

process is set up to bleed off some of the hydrogen to produce the added

energy boost needed to sustain hydrogen production, the process still

creates 144 percent more available energy than the electrical energy used

to produce it. For those who think that a hydrogen economy is far in the future,

Logan suggests that hydrogen produced from cellulose and other renewable

organic materials could be blended with natural gas for use in natural

gas vehicles. " We drive a lot of vehicles on natural gas already. Natural gas

is essentially methane, " says Logan. " Methane burns fairly

cleanly, but if we add hydrogen, it burns even more cleanly and works

fine in existing natural gas combustion vehicles. " The range of efficiencies of hydrogen production based on electrical

energy and energy in a variety of organic substances is between 63 and 82

percent. Both lactic acid and acetic acid achieve 82 percent, while

unpretreated cellulose is 63 percent efficient. Glucose is 64 percent

efficient.

Another potential use for microbial-electrolysis-cell produced

hydrogen is in fertilizer manufacture. Currently fertilizer is produced

in large factories and trucked to farms. With microbial electrolysis

cells, very large farms or farm cooperatives could produce hydrogen from

wood chips and then through a common process, use the nitrogen in the air

to produce ammonia or nitric acid. Both of these are used directly as

fertilizer or the ammonia could be used to make ammonium nitrate, sulfate

or phosphate.

This research is published in the Nov. 12 issue of the Proceedings of

the National Academy of Sciences online. The researchers have filed for a patent on this work. Air Products

and Chemicals, Inc. and the National Science Foundation supported this

work. Adapted from materials provided by Penn State. unAt 08:27 AM 11/16/07, you wrote:

New Method Converts Organic Matter

To Hydrogen Fuel Easily And Effic

Posted by: " Mark Graffis " mgraffis

mgraffis

Thu Nov 15, 2007 5:53 pm (PST)

http://www.sciencedaily.com/releases/2007/11/071112172203.htm

New Method Converts Organic Matter To Hydrogen Fuel Easily And

Efficiently

ScienceDaily (Nov. 13, 2007) — Hydrogen as an everyday, environmentally

friendly fuel source may be closer than we think, according to Penn State

researchers.

" The energy focus is currently on ethanol as a fuel, but economical

ethanol from cellulose is 10 years down the road, " says Bruce E.

Logan, the Kappe professor of environmental engineering. " First you

need to break cellulose down to sugars and then bacteria can convert them

to ethanol. "

Logan and Shaoan Cheng, research associate, suggest a method based on

microbial fuel cells to convert cellulose and other biodegradable organic

materials directly into hydrogen.

The researchers used naturally occurring bacteria in a microbial

electrolysis cell with acetic acid -- the acid found in vinegar. Acetic

acid is also the predominant acid produced by fermentation of glucose or

cellulose. The anode was granulated graphite, the cathode was carbon with

a platinum catalyst, and they used an off-the-shelf anion exchange

membrane. The bacteria consume the acetic acid and release electrons and

protons creating up to 0.3 volts. When more than 0.2 volts are added from

an outside source, hydrogen gas bubbles up from the liquid.

" This process produces 288 percent more energy in hydrogen than the

electrical energy that is added to the process, " says Logan.

 

Water hydrolysis, a standard method for producing hydrogen, is only 50 to

70 percent efficient. Even if the microbial electrolysis cell process is

set up to bleed off some of the hydrogen to produce the added energy

boost needed to sustain hydrogen production, the process still creates

144 percent more available energy than the electrical energy used to

produce it.

For those who think that a hydrogen economy is far in the future, Logan

suggests that hydrogen produced from cellulose and other renewable

organic materials could be blended with natural gas for use in natural

gas vehicles.

" We drive a lot of vehicles on natural gas already. Natural gas is

essentially methane, " says Logan. " Methane burns fairly

cleanly, but if we add hydrogen, it burns even more cleanly and works

fine in existing natural gas combustion vehicles. "

The range of efficiencies of hydrogen production based on electrical

energy and energy in a variety of organic substances is between 63 and 82

percent. Both lactic acid and acetic acid achieve 82 percent, while

unpretreated cellulose is 63 percent efficient. Glucose is 64 percent

efficient.

Another potential use for microbial-electrolysis-cell produced hydrogen

is in fertilizer manufacture. Currently fertilizer is produced in large

factories and trucked to farms. With microbial electrolysis cells, very

large farms or farm cooperatives could produce hydrogen from wood chips

and then through a common process, use the nitrogen in the air to produce

ammonia or nitric acid. Both of these are used directly as fertilizer or

the ammonia could be used to make ammonium nitrate, sulfate or

phosphate.

This research is published in the Nov. 12 issue of the Proceedings of the

National Academy of Sciences online.

The researchers have filed for a patent on this work. Air Products and

Chemicals, Inc. and the National Science Foundation supported this work.

 

Adapted from materials provided by Penn State.

 

 

******

Kraig and Shirley Carroll ... in the woods of SE Kentucky

http://www.thehavens.com/

thehavens

606-376-3363

 

 

 

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